Tailoring the Optical Properties of Polymers Blend Nanocomposites
Source: By:Vibhav Kumar Saraswat
DOI: https://doi.org/10.30564/nmms.v3i1.3391
Abstract:The presented work deals with the structural and optical properties of chemically synthesized TiO2 nanoparticles filled PC/PS blend nanocomposites. A series of PC/PS (100/0, 50/50, 0/100 wt%/wt %) -TiO2 (1, 2, 3 wt %) blend nanocomposites have been prepared by solution casting method. Prepared blend nanocomposites have been subjected to XRD, SEM and FTIR for structural analysis. Optical constants have been analyzed using UV-Vis spectroscopy. The XRD, SEM and FTIR spectrum confirms the formation of PC/PS-TiO2 blend nanocomposites. Results reveal the decrease in band gap and enhancement in optical constants like, extinction coefficient, refractive index and dielectric constants of blend nanocomposites with nanofiller TiO2 content.
References:[1] A. Ariffin, and M. S. B. Ahmad, Polymer-Plastics Technology and Engineering 50, 395 (2011). [2] S. Agarwal, N. S. Saxena, R. Agrawal, and V. K.Saraswat, AIP Conf. Proc. 1536, 777 (2013). [3] S. Agarwal, V. K. Saraswat, International Journal of Engineering Technology, Management and Applied Sciences, 5(7), 2349-4476 (2017). [4] S. Agarwal, Y. K. Saraswat, V.K. Saraswat, Macromol. Symp., 357, 70 (2015). [5] S. Agarwal, Y. K. Saraswat, V.K. Saraswat, Open Physics Journal, 3, 63 (2016). [6] S. Agarwal, V. K. Saraswat, Optical Materials, 42, 335(2015). [7] B. N. Jang, and C. A. Wilkie, Thermochimica Acta 426, 73 (2005). [8] Y. Kitahara, S. Takahashi, M. Tsukagoshi, and T. Fujii Chemosphere 80, 1281 (2010). [9] M. A. Corres, M. Zubitur, M. Cortazar, and A. Mugicaa, Journal of Analytical and Applied Pyrolysis 92, 407 (2011). [10] V. K. Saraswat, V. Kishore, Deepika, K. Sharma, N. S. Saxena, and T. P. Sharma, Chalcogenide Letters 4, 61 (2007). [11] L. F. A. Pinto, B. E. Goi, C. C. Schmitt, and M. G. Neumann, Journal of Research Updates in Polymer Science 2, 39 (2013). [12] M. Pawde, and S. S. Parab, Pramana- Journal of Physics, Indian Academy of Sciences 70, 935 (2008). [13] I. Y. Jeon, and J. B. Baek, Materials 3, 3654 (2010). [14] D. Sun, N. Miyatake, and H. J. Sue, Nanotechnology 18, 1 (2007). [15] D. R. Paul, and L. M. Robeson, Polymer 49, 3187 (2008). [16] L. L. Beecroft, and C. K. Ober, Chem. Mater. 9, 1302 (1997). [17] B. Wetzel, F. Haupert, K. Friedrich, M. Zhang, and M. Rong, Polym. Eng. Sci. 42, 1919 (2002). [18] C. B. Ng, B. J. Ash, L. S. Schadler, and R. W. Siegel, Adv.Compos. Lett. 10, 101 (2001). [19] R. Lane, B. Craig, and W. Babcock, AMPTIAC Newslett. 6, 31 (2002). [20] T. C. Dang, D. L. Pham, H. C. Le, and V. H. Pham,Adv. Nat. Sci.: Nanosci. Nanotechnol. 1,1 (2010). [21] M. M. Khan, S. A. Ansari, J. Lee, and M. H. Cho, Journal of Industrial and Engineering Chemistry 19,1845 (2013). [22] G. M. Herrera-Sandoval, D. B. Baez-Angarita, S. N. Correa-Torres, O. M. Primera-Pedrozo, and S. P. Hernández-Rivera, Materials Sciences and Applications 4, 179 (2013). [23] U. Diebold, Surface Science Reports 48, 53 (2003). [24] H. Agrawal, K. Awasthi, and V. K. Saraswat, Polym. Bull. 71, 1539 (2014). [25] M. M. El-Desoky ,I.M. Morada, M. H. Wasfya, A.F. Mansourb, IOSR Journal of Applied Physics 9(5), 33( 2017). [26] M. T. Ramesan, Polymer-Plastics Technology and Engineering 51, 1223 (2012). [27] B. Jaleha, M. S. Madada, M. F. Tabrizib, S. Habibia, R. Golbedaghic, and M. R. Keymaneshd, J. Iran.Chem. Soc. 8, S161 (2011). [28] R. Liu, Materials 7, 2747 (2014). [29] O. G. Abdullah, Wasit Journal for Science & Medicine 4,1 (2011). [30] V. Kulshrestha, G. Agarwal, K. Awasthi, B. Tripathi, N. K. Acharya, D. Vyas, V. K. Saraswat, Y. K. Vijay, and I. P. Jain, Micron 41, 390 (2010). [31] P. H. Borse, L. S. Kankate, F. Dassenoy, W. Vogel, J. Urban, S. K. Kulkarni, Journal of Material Science: Materials in Electronics 13, 553 (2002) [32] F. L. Rashid, A. Hashim, M. A. Habeeb, S. R. Salman, and H. Ahmed, Chemistry and Materials Research 3, 55 (2013). [33] R. Das, and S. Pandey, International Journal of Material Science 1, 35 (2011). [34] J. Tauc, A. Menth, and D. Wood, Phys. Rev. Lett. 25, 749 (1970). [35] Rouaramadan, Ekramajaj, and A. A. Hasan, International Journal of Application or Innovation in Engineering & Management 2, 240 (2013). [36] K. A. Ammar, A. Hashim, and M. Husaien, Chemical and Materials Engineering 1, 85 (2013). [37] M. M. Abdul-Gader Jafar, European International Journal of Science and Technology 2, 214 (2013). [38] W. A. Taa’y, M. A. Nabi, R. M. Yusop, E. Yousif, B. M. Abdullah, J. Salimon, N. Salih, and S. I. Zubairi, International Journal of Polymer Science (2014) doi./10.1155/2014/697809. [39] Qiu S, and Kalita S ,J Mater Sci Eng A 327, 435 (2006). [40] C.Lu., and B. Yang, J.Matter.Chem., 19, 2884(2009). [41] Smita Dayal, Nikos Kopidakis, Dana C. Olson, David S. Ginley, and Garry Rumbles, Nano Lett. 10, 239 (2010). [42] Chih-Ping Chen, Shu-Hua Chan, Teng-Chih Chao, Ching Ting, and Bao-Tsan Ko, J. Am. Chem. Soc.130, 12828 (2008)