Extraction of Dyes from Sunflower Petal and Their Fourier Transform Infrared Characterization

Updata:01-01-1970

Source:
By:Authors

DOI: https://doi.org/10.30564/opmr.v3i1.2586

Abstract:
Three solvents of different polarities (water, methanol and 1% NaOH
solution) were used to extract dyes that produced different shades from
dried sunflower (Helianthus annuus) petal. The extraction procedures
using different solvent types were carried out separately. The dye extracts
were thereafter subjected to Fourier Transform Infrared Spectrometry
(FT-IR) analysis for characterization in terms of functional groups. The
intensities of the extracted dyes on the shade of colours obtained on pieces
of cotton material varied from yellow in methanolic extract to light yellow
in aqueous and black in 1% NaOH solution extracts. The results obtained
from the FT-IR analysis revealed the presence of several useful functional
groups such as N-H, C=H, O-H and C=O in the extracts.
References:

[1] Rauf, M.A., Soliman, A.A., Khattab, M., 2008. Solvent effect on the spectra properties of neutral red. Chem. Central J. 2, 19. [2] Adeoye, M.D., Abdulsalami, I.O., Oyeleke, G.O., Alabi, K.A., 2019. Theoretical studies of solvent effects on the electronic properties of 1, 3-Bis [(Furan-2yl) Methylene] Urea and Thiourea”, J. Phys & Theor. Chem. of Islamic Azad University of Iran. 15(3, 4), 115-125. [3] Ondarroa, M., Sharma, S.K., Quinn, P.J., 1986. Solvation properties of Ubiquinone-10 in solvents of different polarity. Biosci. Rep. 6(9), 783-796. [4] Homocianu, M., Airinei, A., Dorohoi, D.O., 2010. Solvent effects on the electronic absorption and fluorescence spectra. J. Adv. Res. Phys. 2(1), 011105. [5] Targema, M., Obi-Egbedi, N.O., Adeoye, M.D., 2013. Molecular structure and solvent effects on the dipole moments and polarizabilities of some aniline derivatives. Comput. & Theor. Chem. 1012, 47-53. [6] Khan, M.F., Rashid, R.B., Rahman, M.M., Al Faruk, M., Rahman, M.M., Rashid, M.A., 2017. Effects of solvent polarity on solvation free energy, dipole moment, polarizability, hyperpolarizability and molecular reactivity of Aspirin. Int. J. Pharm. Sci. 9, 217- 221. [7] Saravanan, P., Chandramohan, G., Saivaraj, S., Deepa, D., 2013. Extraction and application of eco-friendly natural dye obtained from barks of Odina wodier L on cotton fabric. Scholar Res. Lib. 3, 80- 85. [8] Nurunnesa, Hossain, M.A., Rahman, M.M., 2018. Extraction of natural dye collected from the outer skin of onion and it’s applications on skin fabric. Global J. Res. Eng. 18(3 Ver. 1), 1-6. [9] Samanta, A.K., Konar, A., 2011. Dyeing of textiles with natural dyes. In: Kumbasar, E.A., Ed., Natural Dyes, Intech Open, London. 29-56. [10] Uddin, M.D., Razzaq, M.A., Quadery, A.H., Chowdhury, M.J., Al-Mizan, Raiman, M.M., Ahmad, F., 2017. Extraction of dye from natural source (LAC) and its application on leather. Amer. Sci. Res. J. Eng., Technol. & Sci. 34(1), 1-7. [11] Saravanan, P., Chandramohan, G., Mariajacyrani, J., Saivaraj, S., 2015. Effect of chitosan and mordants on the dyeability of cotton fabrics with a natural dye from the barks of Odina wodier Roxb. J. Indian Chem. Soc. 92(6), 1007-1007. [12] Saravanan, P., 2013. A study on the extraction and application of eco-friendly natural dye from barks of Odina wodier on silk fabric. Int. J. Curr Res. 5(5), 1070-1073. [13] Saravanan, P., Chandramohan, G., Saivaraj, S., 2012. A study on the eco-friendly natural dye extracted from flowers of Lanntana camara L. on silk and wool fabrics. Asian J. Res. Chem. 5(3), 418-421. [14] Nnorom, O.O., Onuegbu, G.C., 2019. Authentication of Rothmannia whitfieldii dye extract with FTIR Spectroscopy. J. Tex. Sci. & Techn. 5, 38-47. [15] Olajire, A.A., 2011. Principles and applications of spectroscopic techniques. Ibadan, Ogfat Publications. [16] Yuen, C.W.M, Ku, S.K.A., Choi, P.S.R., Kan,C.W., Tsang, S.Y., 2005. Determining functional groups of commercially available ink-jet printing reactive dyes using infrared spectroscopy. Res. J. Tex. & Apparel. 9(2), 26-38. [17] Ashokkumar, R., Ramaswamy, M., 2014. Phytochemical screening by FTIR spectroscopic analysis of leaf extracts of selected Indian medicinal plants. Int. J. Cur. Microbiol. & Appl Sci. 3(1), 395-406. [18] Kakeru, P.G., Keriko, G.J.M. Kenji, A.N., 2008. Direct detection of triterpenoid saponins in medicinal plants. Afr. J. Trad., Complem. & Altern. Med. 5(1), 56-60. [19] Charushila, D., Swaroopa, P., 2016. FT-IR spectroscopic screening of phytochemicals of two medicinally important species of Solanum used in preparation of Dashmula formulation. Int. J. Pharm. Sci. & Res. 36(2), 112-120. [20] Pakkirisamy, M., Kalakandan, S.K., Ravichandran, K., 2017. Phytochemical screening, GC-MS, and FTIR analysis of methanolic extract of Curcumia caesia Roxb (Black turmeric). Pharmacog. J. 9(6), 952-956. [21] Sayani, C., 2019. Fourier transform infrared (Ft-ir) spectroscopic analysis of Nictianaplum baginifolia (Solanaceae). J. Med. Plant Studies. 7(1), 82-85. [22] Popoola, A.V., 2015. Chemistry of colours in dyes and pigments. (Allen, TX US & Lagos, Nigeria). Wits Publishing Ltd. 1-40. [23] Shin, Y., Yoo, D., 2012. Storage stability and colour reproducibility of yellow and red dyes extracted from Carthamus tinotorius L. J. Tex. Colora. & Finish. 24(3), 155-172. [24] Coates, J., 2000. Interpretation of infrared spectra. A practical approach. In: Meyers, R.A., Ed., Encyclopedia of analytical chemistry, John Wiley and Sons Ltd., Chichester. 1-23.

Tags: